Product ID:NYEBAR TYPE W
MSDS Date:09/26/1991
FSC:6850
NIIN:00N010610
MSDS Number: CBVQJ

Emergency Phone: 508-758-4408; 508-993-485

Info Phone: 508-996-6721

Preparer: GBM

Cage: 98354

Telephone: 508-996-6721

Cage: 98354

ETHANE, 1,1,2-TRICHLORO-1,2,2-TRIFLUORO-;

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 9.9%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 1250 STEL

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROFLUOROCARBON (CFC) MATLS HAVE
PRODUCED SENSIT OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &
COULD HAVE A SIMILAR EFT IN HUMANS. ADRENOMIMETICS (IE,
EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEP T FOR LIFE-SUSTAINING
USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED TO CFCS . A PORTION
OF THIS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: MATL AS SUPPLIED IS A VOLAT SOLV.
VAPS CAN REDUCE THE AMT OF OXYGEN AVAIL FOR BRTHG. OVEREXP CAN
CAUSE LIGHT HEADEDNESS, GIDDINESS, SHORTNESS OF BREATH, POSSIBLE
NARCOSIS & POSS CARDIAC ARRH YTHMIAS AT HIGH CONCENTRATIONS.
PROLONGED OR REPEATED SKIN CONTACT OR EYE CONTACT CAN CAUSE
IRRITATION.
Medical Cond Aggravated by Exposure:NONE.

First Aid:EYES: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. INHALATION:
REMOVE TO FRESH AIR AND CALL MD. DO NOT GIVE EPINEPHRINE OR SIMILAR
DRUGS. INGES TION: DO NOT INDUCE VOMITING; CONTACT MD IMMEDIATELY.
EXERCISE ORDINARY MEASURES OF PERSONAL HYGIENE. AVOID CONTAMINATION
OF CIGARETTES OR OTHER TOBACCO PRODUCTS.

Flash Point:NON-FLAMMABLE
Extinguishing Media:NOT FLAMMABLE. MEDIA SUITABLE FOR SURROUNDING FIRE
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT . AVOID INHALATION OF VAPOR OR SMOKE.
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCL FLUORIDES,
CHLORIDES & PHOSGENE . IF HEATED TO DECOMP (>300C) WHILE SOLV IS
STILL PRESENT, DANGEROUS HALOGENATED (SUPDAT)

Spill Release Procedures:REMOVE FREE LIQUID. VENTILATE AREA, ESPECIALLY
LOW PLACES WHERE VAPORS MIGHT COLLECT. REMOVE OPEN FLAMES. AFTER
REMOVING FREE SOLVENT, WASH WALKING SURFACES THOROUGHLY WITH
DETERGENT AND WATER TO REDU CE SLIPPING HAZARD.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. DO NOT
ALLOW STORAGE TEMPERATURES TO RISE ABOVE 80F. OPEN ONLY IN WELL
VENTILATED AREAS.
Other Precautions:NO SMKNG IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING, OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE
FORM OF CHLORIDES, FLUORIDES OR PHOSGENE . AVOID CONTAM OF
CIGARETTES/OTHER T OBACCO PRODS. WASH HANDS THORO (SUPDAT)

Respiratory Protection:USE NIOSH/MSHA APPROVED AIR MASK AS NECESSARY TO
AVOID INHALATION OF SOLVENT VAPORS. VAPOR REDUCES OXYGEN AVAILABLE
FOR BREATHING.
Ventilation:MUST BE PROVIDED AS NECESSARY TO REMOVE EVAPORATING SOLVENT
VAPORS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VP: 7.856 PSIA @ 30C. EXPLO HAZ: PRODS MAY FORM. OTHER PRECS: BEFORE
SMOKING. USERS SHOULD BE ALERT TO POSSIBILITY THAT VERY SMALL
PERCENTAGES OF POPULATION MAY DISPLAY UNEXPECTED ALLERGIC SKIN
REACTI ONS TO OTHERWISE INNOCUOUS INDUSTRIAL CHEMICALS & RAW
MATERIALS.

Boiling Pt:B.P. Text:194F,90C
Vapor Pres:SUPDAT
Vapor Density:HVR/AIR
Spec Gravity:1.677
pH:NEUT
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR, COLORLESS FLUID.
Percent Volatiles by Volume:99.82

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:OPEN FLAMES OR HIGH TEMPERATURES.
Hazardous Decomposition Products:CHLORIDES, FLUORIDES . HYDROCHLORIC &
HYDROFLUORIC ACID, CARBON MONOXIDE, POSSIBLE PHOSGENE & OTHER TOXIC
GASES.

Waste Disposal Methods:MATERIAL MUST BE DISPOSED OF BY A LICENSED FIRM
AS "HAZARDOUS WASTE." CONSULT LOCAL, STATE AND FEDERAL REGULATIONS
APPLICABLE TO YOUR AREA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.